Physical Chemistry – Gilbert William Castellan – 2nd Edition


Chemistry provides students with an in-depth fundamental treatment of physical chemistry. At the same time, the treatment is made easy to follow by giving full step-by-step derivations, clear explanations and by avoiding advanced unfamiliar to students. Necessary math and have thorough review sections. Worked examples are followed by a exercise.

chemistry is the quantitative study of the physical properties of matter, including their transformations. The properties of macroscopic matter at equilibrium (such as the relationships among temperature, pressure, and volume in gases; heat capacity of solids; solubility of saturated solutions; melting and boiling temperatures; and behavior of electrolyte solutions, to name a few) are historically among the earlier interests of physical chemistry. All of the examples mentioned just above belong to the subject of thermodynamics, a remarkable science which unified a wide variety of empirical laws under the broader concepts of energy and entropy.

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  • Some Fundamental Chemical Concepts
    Empirical Properties of Gases
    Real Gases
    The Structure of Gases
    Some Properties of Liquids and Solids
    The Laws of Thermodynamics: Generalities and the Zerothe Law
    Energy and the First Law of Thermodynamics: Thermochemistry
    Introduction to the Second Law of Thermodynamics
    Properties of the Entropy and the Third Law of Thermodynamics
    Spontaneity and Equilibrium
    Systems of Variable Composition: Chemical Equilibrium
    Phase Equilibrium in Simple Systems: The Phase Rule
    Solutions ? The ideal Solution and Colligative Properties
    Solutions ? More Than One Volatile Component; The ideal Dilute Solution
    Equilibria Between Condensed Phases
    Equilibria in Nonideal Systems
    Equilibria in Electronchmical Cells
    Surface Phenomena
    The Structure of Matter
    Introduction to Quantum Mechanical Principles
    The Quantum Mechanics of Some Simple Systems
    The Hydrogen Atom
    The Covalent Bond
    Atomic Spectroscopy
    Molecular Spectroscopy
    Intermolecular Forces
    Structure of Solids
    Electronic Structure and Macroscopic Properties
    Structure and Thermodynamic Properties
    Transport Properties
    Electrical Conduction
    Chemical Kinetics ? Empirical Laws and Mechanism
    Chemical Kinetics ? Theoretical Aspects
    Chemical Kinetics ? Heterogeneous Reactions, electrolysis, Photochemistry
  • Citation

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